Vino Nobile di Montepulciano DOCG and Toscana IGTSangiovese (Prugnolo Gentile), Cabernet Sauvignon, Merlot, Canaiolo Nero130 haFounded 1961Carletti family (Federico Carletti, owner)Winemaker Federico CarlettiVino Nobile di Montepulciano DOCG
Carletti family estate founded 1961 at the foot of Montepulciano. The Asinone single-vineyard Vino Nobile, named after the donkey-shaped hillside, is among the most consistently reviewed wines of the DOCG.
Tasting: Cellar tours and tasting flights by appointment; the Asinone single-vineyard Vino Nobile is the flagship.
Signature wines: poliziano-asinone, poliziano-vino-nobile, poliziano-le-stanze
Scores: Wine Advocate 94 (2019), Vinous 94 (2018)
Bolgheri Sassicaia DOC (single-estate DOC, established 1994)Cabernet Sauvignon, Cabernet Franc90 haFounded 1944Incisa della Rocchetta family (Marchese Nicolo Incisa della Rocchetta, president)Winemaker Carlo Paoli (estate manager) with Graziana Grassini consultingBolgheri Sassicaia DOC
The Bolgheri estate where Mario Incisa della Rocchetta planted Bordeaux cuttings in 1944. First released as Sassicaia 1968; awarded its own Bolgheri Sassicaia DOC in 1994.
Tasting: Strictly limited visits; the estate prioritises trade and allocation customers. Public access is rare.
Signature wines: sassicaia, guidalberto, le-difese
Scores: Wine Advocate 100 (1985)
Bolgheri Superiore DOC and Toscana IGTCabernet Sauvignon, Merlot, Cabernet Franc, Petit Verdot, Sauvignon Blanc115 haFounded 1981Frescobaldi family (acquired full ownership 2005)Winemaker Marco Balsimelli (estate director); Olga Fusari, head winemakerICEABolgheri DOC
Bolgheri estate founded by Lodovico Antinori in 1981 and fully owned by Frescobaldi since 2005. Bordeaux-cloned reds with Masseto and Ornellaia as flagships; the estate is ICEA-organic certified.
Tasting: Cellar tours, vineyard walks and tutored tastings by appointment; the Vendemmia d'Artista label programme is on display at the cellar.
Signature wines: ornellaia, le-volte-dell-ornellaia, ornellaia-bianco, le-serre-nuove-dell-ornellaia
Scores: Wine Spectator 96 (1998), Wine Advocate 98 (2015)
Toscana IGTMerlot7 haFounded 1986Frescobaldi familyWinemaker Eleonora MarconiICEABolgheri DOC
A 7-hectare blue-clay Merlot parcel inside the Ornellaia estate. First released as a separate brand in 1986. Now operates with its own dedicated cellar opened in 2020; widely considered Italy's most prestigious Merlot.
Tasting: Visits to the dedicated Masseto cellar by very limited appointment; one of Italy's hardest-to-secure cellar tours.
Signature wines: masseto, massetino
Scores: Wine Advocate 98 (2001), Wine Advocate 100 (2015)
Bolgheri Superiore DOC and Toscana IGTCabernet Sauvignon, Merlot, Cabernet Franc, Petit Verdot, Vermentino, Syrah320 haFounded 1990Marchesi Antinori (the Antinori family's Bolgheri estate, separate producer slug from Marchesi Antinori in Chianti Classico)Winemaker Renzo Cotarella (Antinori chief winemaker); Pierluigi Talamo, estate directorBolgheri DOC
Antinori's Bolgheri estate, established as a standalone vineyard in 1990 from the family's 1932 land purchase. 320 hectares; Guado al Tasso Superiore is flagship.
Tasting: Cellar visits, vineyard walks and the Osteria Magona village kitchen at Bolgheri; bookings via the Antinori hospitality desk.
Signature wines: guado-al-tasso, il-bruciato, scalabrone, matarocchio
Scores: Wine Advocate 97 (2015), Vinous 97 (2018)
Bolgheri DOC and Toscana IGTCabernet Franc, Merlot, Syrah, Sangiovese22 haFounded 1983Cinzia Merli and family (widow of co-founder Eugenio Campolmi)Winemaker Cinzia Merli with Luca d'Attoma consultingCCPBBolgheri DOC
Family estate founded 1983 by Eugenio Campolmi; Cinzia Merli has led the property since his death in 2002. Single-varietal Cabernet Franc (Paleo), Merlot (Messorio) and Syrah (Scrio) bottlings; CCPB-organic certified.
Tasting: Cellar visits and tutored tastings by appointment; vegan vinification practices used since 2014.
Signature wines: le-macchiole-paleo-rosso, le-macchiole-messorio, le-macchiole-scrio, le-macchiole-bolgheri-rosso
Scores: Wine Advocate 97 (2015), Vinous 96 (2019)